How does the user set the time? Is it "real time" so like they enter when they start at the time they start or do they add it in at some other time? If it is real time, then you can just have a button which adds the date and time by using NOW.
Code:
Private Sub YourButtonNameHere_Click()
Me!StartDateTimeFieldNameHere = Now
End Sub
If at another time, you can use a date/time picker to select the date and then an unbound text box where they enter the time only and in the After Update of that text box you could use:
Code:
Private Sub UnBoundTextboxNameHere_AfterUpdate()
Me!YourDateTimeFieldNameHere = Me.DatePickerNameHere.Value + Me.UnBoundTextBoxNameHere
End Sub