I
never use multi value fields.
I second and third that notion!
The original table has the values sorted ascending correctly. I have retyped the erring values
If you mean the table that you see, then from what little I know of these fields I'd say it's because what you see is actually a representation of the REAL tables that you can't see, which Access creates for MVF's. Apparently, you can successfully sort the representation in a table view, but the hidden tables are the ones that you are pulling the data from when you query or report. One thing you can try is to query the MFV table and apply a sort, then base your report on another query that uses the sorting query as a table. As inferred, what I know of these fields is from whatever I've read about them - foremost which was to never use them.
The more we hear silence, the more we begin to think about our value in this universe.
Paraphrase of Professor Brian Cox.