It should just be a matter of taking the criteria that rpears gave you in his SQL code, and updating the PurchaseDate field with the calculation.
The SQL Code could look something like this:
Code:
UPDATE Production_Schedule
SET PurchaseDate = StartDate - 2
WHERE (((Production_Schedule.PW) Is Null) AND ((Production_Schedule.StartDate)>#1/1/2014#));
If you paste this in the SQL View of the Query Builder and save it, it should work.
If you do a Google Search on "Access Update Query", you can find lots of information, tutorials, and videos about creating Update Queries using the Query Builder.