Since I received such helpful feedback before I thought I would try this again. A few notes before I ask my question, I did not build the database so I am just doing my best to work with how the database is set up, and I know that I am using names that would not be recommended for proper naming conventions.
In the pictures above I have a dataset that uses duplicate values for each record. The purpose of that was (I believe) to include the data for a specific site from two different forms on one table in access. In addition to that I have a presence/absence box, that at least in this example is checked for each record (that is not always the case). What I am trying to accomplish, is to fill the 3rd column over from the check boxes with values from the Species_List table from the Final C_Value field. When I try a outer join as you can see in the second picture the query returns many more duplicates than the original has, as seen in the 3rd picture. The goal is to fill each VP1_SP#_CofC column in the Intensive_VegPlot_1 table with the corresponding Final C_Values from the Species_List table. I am assuming that I am going to have to build upon queries to fill each column.
Any help would be appreciated