Looks like a closing parenthesis might be in the wrong place.
You have
Code:
Me.txtJanPayOut.Value = Nz(DSum("poValue", "tblTrackingDelivery", "Month(payVendorNLTDate) = 1", 0))
Try
Code:
Me.txtJanPayOut = Nz(DSum("poValue", "tblTrackingDelivery", "Month(payVendorNLTDate) = 1"), 0)
Don't need ".Value"..... it is the default property. Doesn't hurt - just extra typing. 
Edit......Does "payVendorNLTDate" have a year component?. Might have to add the year to limit the DSum to a specific year.
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Without NZ(): DSum("poValue", "tblTrackingDelivery", "Month(payVendorNLTDate) = 1")
Adding NZ(): NZ(DSum("poValue", "tblTrackingDelivery", "Month(payVendorNLTDate) = 1"),0)